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4.4: Oxidation / Reduction Reactions

REDOX REACTIONS


OXIDATION:
Increase in Oxygen numbers
Reduce number of Hydrogens
Increase Oxidation numbers
Remove electrons

REDUCTION:
Decrease Oxygen numbers
Increase Hydrogen numbers
Decrease Oxidation numbers
Add electrons

ASSIGNING OXIDATION NUMBERS

1. Any substance in elemental form = 0    
Example:
O2, Na, S8, P4


2. Monoatomic ion oxydation number equal to its charge
Example:

F⁻' = - 1


3. Oxygen and Hydrogen's oxydation numbers are as follows:

O = -2
H = +1 (when it's paired with a non-metal)
H = -1 (when it's paired with a metal)

4. Sum of oxydation numbers:
Compound sum = 0
Polyatomic ion sum = charge of ion


Exercise:
Obtain the oxidation number of the bold element:


PO
2P + 5O = 0
2P + 5 x -2 = 0
2P -10 = 0
P = +5


CrO₇⁻²
2Cr + 7O = -2
2Cr + (7 x -2) = -2
2Cr - 14 = -2
2Cr = 12
Cr = 6

DISPLACEMENT REACTIONS

(Single Replacement Reactions example of Redox reactions)





ACTIVITY SERIES
 Exercise:
 Write the products of the following reactions:

Zn + Pb(NO)  ----> Zn(NO) + Pb
Zn > Pb on Activity series, therefore the reaction occurs.

Cu + Pb(NO) ----> NR
Cu > Pb on Activity series, therefore there’s no reaction


Exercise:
Write what compound gets oxidized and which compound get reduced in the following displacement reaction:

Al + 6HBr ----> H2 + AlBr3

Procedure:
 

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